DEPARTMENTS
Dr. Anuj A. Vargeese
Dr. Anuj A. Vargeese

Assistant Professor

Office Address:

Room No 210 (d), Laboratory for Energetic and Energy Materials Research (LEEMR), Department of Chemistry, National Institute of Technology Calicut, Kozhikode / Calicut 673 601, Kerala

  • Ph. D. (University of Pune) Title of the Thesis: Studies on the crystal habit modification and morphology control of Ammonium Nitrate and Ammonium Perchlorate

  • M. Sc. (University of Pune) Title of the Thesis: Development of silicone based inhibitor for solid propellants

  • Educational Qualifications

    • Ph. D. (University of Pune) Title of the Thesis: Studies on the crystal habit modification and morphology control of Ammonium Nitrate and Ammonium Perchlorate

    • M. Sc. (University of Pune) Title of the Thesis: Development of silicone based inhibitor for solid propellants

    Journals

    International Journals

    2024

    C. Shamjitha., Anuj A Vargeese*, Copper–Cobalt Oxide Nanoparticles with Tailored Cobalt Oxidation State and Lattice Oxygen Vacancy for Low-Temperature Ignition of Ammonium Dinitramide Monopropellants, ACS Appl. Nano Mater., Accepted (2024)

    2023
    27) C. Shamjitha., Anuj A Vargeese*, Development of bimetallic spinel catalysts for low-temperature decomposition of ammonium dinitramide monopropellants, Def. Technol., 30, 47, (2023)

    2022
    26) Anusree T. C., Anuj A Vargeese*, Enhanced performance of barium and cobalt doped spinel CuCr2O4 as decomposition catalyst for ammonium perchlorate, J. Solid State Chem., 315, 123481 (2022) 
    25) Soumee Chakraborty, R. Rajitha, V. Venkatesan, Anuj A. Vargeese, Raja R. Madhavan, R. Asuvathraman, and T. R. Ravindran, Elastic and phonon-mode anomalies with temperature in the energetic material C  6  H 6 N4O8 (TEX) , Phys. Rev. B: Condens. Matter Mater. Phys.105, 134105 (2022)
    24) Rajitha Rajan, T. R. Ravindran, , Nagarjuna Kommu, Anuj A. Vargeese, P. Anees, V. Venkatesan, and V. Srihari, Phase transformation of heat-resistant energetic material BDNAPM studied by Raman spectroscopy and X-ray diffraction, J. Mater. Sci., 57, 6115–6128, (2022)
     

    2020
    23)  Mohammad Khaja,   Vikranth Thaltiri,   Nagarjuna Kommu, Anuj A Vargeese*, Octanitropyrazolopyrazole: A Gem-trinitromethyl Based Green High-Density Energetic Oxidizer, Chem. Commun., 56, 12945-12948, (2020).
    22) G. Rajanna, Macharla Arun Kumar, Kranthi Chatragadda, Anuj A Vargeese,* Catalytic Decomposition Mechanism of Aqueous Ammonium Dinitramide Solution Elucidated by Thermal and Spectroscopic Methods, Thermochim. Acta, 686, 178544 (2020).
     

    2019
    21) Rajitha Rajan, T. R. Ravindran,* R. Raja Madhavan, R. Asuvathraman, Sharat Chandra, V. Venkatesan, and Anuj A. Vargeese, Thermal expansion of energetic material TEX obtained from x-ray diffraction and first principles calculations, J. Mol. Struct. 1195, 859 (2019).
    20) Anuj A.Vargeese*, Decomposition kinetics of substituted energetic isowurtzitane cage molecules hexanitrohexaazaisowurtzitane (CL20) and TEX: A comparative study, ChemistrySelect, 4, 6821, (2019).
    19) Macharla Arun Kumar, Parimi Ashutosh, Anuj A.Vargeese*, Decomposition mechanism of hexanitrohexaazaisowurtzitane (CL-20) by coupled computational and experimental study, J. Phys. Chem. A, 123, 4014, (2019) .
     

    2018
    18) Parimi Ashutosh, Anuj A Vargeese*, Experimental and Computational Investigation on the Decomposition Kinetics and Uni-Molecular Degradation of (Z)-N,2,2,2-tetranitroacetimidic acid, J. Anal. Appl. Pyrolysis, 135, 281, (2018) .
    17) R. Rajitha, T. Ravindran*, V. Venkatesan, V. Srihari, P. Krishan, C. Sharat, M. Karuna, Anuj A Vargeese, New High Pressure Phases of Energetic Material TEX: Evidence from Raman Spectroscopy, X-ray Diffraction and First Principles Calculations, J. Phys. Chem. A, 122, 6236, (2018).
     

    2017
    16) Pankaj Gaur, Sagarika Dev, Sunil Kumar, Mahesh Kumar, Anuj A. Vargeese, Pramod Soni, Prem Felix Siril*, and Subrata Ghosh*, Dendritic Polynitrato Energetic Motifs: Development and Exploration of Physicochemical Behavior through Theoretical and Experimental Approach, ACS Omega 2, 8227, (2017).
    15) Kranthi Chatragadda, Anuj A Vargeese,* Synergistically Catalysed Pyrolysis of Hydroxyl Terminated Polybutadiene Binder in Composite Propellants and Burn Rate Enhancement by Free-Standing CuO Nanoparticles, Combust. Flame, 182, 28, (2017)
    14) Kranthi Chatragadda, Anuj A Vargeese,* A Kinetics Investigation on the Nitro-Nitrite Rearrangement Mediated Thermal Decomposition of High Temperature Monoclinic Phase of 1,1-Diamino-2,2-Dinitroethylene (g-Fox-7), J. Chem. Sci., 129, 281, (2017)
     

    2016
    13)Santhosh Reddy Mandha, Anuj A Vargeese,* Thermal decomposition kinetics of 4,10-Dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.05,903,11]dodecane (TEX) : An energetic nitramine oxidizer, (Invited Article), ITAS Bulletin, 8, 16, (2016).
    12) Anuj A. Vargeese,* A kinetic investigation on the catalytic activity of copper oxide nanorods on the thermal decomposition of composite propellants, Combust. Flame, 165, 354, (2016).
     

    2015
    11) Anuj A. Vargeese,* Pressure effects on the thermal decomposition reactions: A thermo-kinetic investigation, RSC Adv., 5, 78598, (2015). .
    10) Anuj A. Vargeese,* K. Muralidharan, V. N. Krishnamurthy, Kinetics of nano titanium dioxide catalyzed thermal decomposition of ammonium nitrate and ammonium nitrate based composite solid propellant, Propellants Explos. Pyrotech. 40, 260, (2015) .
     

    2014
    9) Anuj A. Vargeese,* Mija S. J., K. Muralidharan, Effect of Copper Oxide, Titanium Dioxide, and Lithium Fluoride on the Thermal Behaviour and Decomposition Kinetics of Ammonium Nitrate, J. Energetic Mater, 32, 146, (2014).
     

    2013
    8) Anuj A. Vargeese,* Krishnamurthi Muralidharan*, Effect of anatase-brookite mixed phase titanium dioxide nanoparticles on the high temperature decomposition kinetics of ammonium perchlorate, Mater. Chem. Phys., 139, 537, (2013).
     

    2012
    7) Anuj A. Vargeese,* K. Muralidharan, Kinetics and mechanism of hydrothermally prepared copper oxide nanorod catalyzed decomposition of ammonium nitrate, Appl. Catal., A, 447-448, 171, (2012).
    6) P. Ravi,* Anuj A. Vargeese, S. P. Tewari, Isoconversional kinetic analysis of decomposition of nitropyrazoles, Thermochim. Acta, 550, 83, (2012).
     

    2011
    5) Anuj A. Vargeese,* K. Muralidharan, V. N. Krishnamurthy, Thermal Stability of habit modified ammonium nitrate: Insights from isoconversional kinetic analysis, Thermochim. Acta, 524, 165, (2011).
    4) Anuj A. Vargeese,* K. Muralidharan, Anatase-brookite mixed phase nano TiO2 catalyzed homolytic decomposition of ammonium nitrate, J. Hazard. Mater., 192, 1314, (2011).
     

    2010
    3) Anuj A. Vargeese, Satyawati S. Joshi,* V. N. Krishnamurthy, Use of potassium ferrocyanide as habit modifier in the size reduction and phase modification of ammonium nitrate crystals in slurries, J. Hazard. Mater., 180, 583, (2010).
     

    2009
    2) Anuj A. Vargeese, Satyawati S. Joshi,* V. N. Krishnamurthy, Effect of method of crystallization on the IV–III and IV–II polymorphic transitions of ammonium nitrate, J. Hazard. Mater., 161, 373, (2009).
     

    2008
    1) Anuj A. Vargeese, Satyawati S. Joshi,* V. N. Krishnamurthy, Role of Poly(vinyl alcohol) in the Crystal Growth of Ammonium Perchlorate, Cryst. Growth Des. 8, 1060, (2008).

    Books (Refereed)

    Book Chapters

    Professional Experience

    • Assistant Professor (Feb 2020 -Present) Department of Chemistry, National Institute of Technology Calicut (NIT Calicut)

    • Assistant Professor (May 2017-Feb 2020) Nanomaterials and Propellant Chemistry Laboratory Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad

    • Scientist (Co-terminus) (September 2014 - April 2017) Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad

    • Adhoc Lecturer (July 2011 - September 2014) Department of Chemistry National Institute of Technology Calicut

    • PURSE Postdoctoral Fellow (June 2010 - July 2011) With Prof. K. Muralidharan School of Chemistry & Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad

    • Research Associate (June 2009 - June 2010) With Prof. K. Muralidharan Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad

    • CY7356: Advanced Materials, M. Sc. Chemistry (Semester IV), Department of Chemistry/ NIT Calicut

    • CY-806: Instrumental Methods -B: Thermal Analysis and Calorimetry, Ph. D course work School of Chemistry/ University of Hyderabad  

    • AC810: Introduction to High Energy Materials, Ph. D course work (Semester I), ACRHEM/ University of Hyderabad

    • CY 7204: Solid State Chemistry, M. Sc. Chemistry (Semester III), Department of Chemistry/ NIT Calicut

    • CY 6203: Chemical and Statistical Thermodynamics, M. Sc. Chemistry (Semester I), Department of Chemistry/ NIT Calicut

    • SHG 301: Materials Chemistry, B. Tech (Semester V), Eng. Physics/ NIT Calicut

    • CY 2001: Physical Chemistry, B. Tech (Semester III), Chem. Eng. & Eng. Physics/ NIT Calicut

    • CY 1001:Chemistry, B. Tech (Semester I), Electronics/Electrical Engineering Department/ NIT Calicut

    • AC-828: Characterization of high energy materials, Ph. D course work (Semester I), ACRHEM/ University of Hyderabad

    Major Research Interests

    Dr. Anuj works on the development of materials for energetic applications. Major research interests include synthesis and applications of energetic nanomaterials, synthesis and applications of green oxidizers, development of green propellants and understanding the kinetics and mechanism of energetic material decomposition.

    Specialization
    Energetic Materials
    Energetic Nanomaterials


    Current Research Interests
    Green Oxidizers
    3DOM mixed metal oxides
    Nanothermites

     

    Development of Energetic Nanomaterials and Nanocatalysts

     

    Development of Energetic Oxidizers

     

    Development of Thermoelectric Generators (TEGs)   

     

    Kinetics and Mechanism of Energetic Materials Decomposition

     

    Combustion Chemistry of Solid propellants  

     

    Life time prediction and Hazardous assessment of Energetic Materials

    Group Members

    Doctoral Students

    1. Shamjitha C

    Fellowship: JRF (CSIR)
    MPhil.: Cochin University of Science and Technology (CUSAT)
    Post Graduation: Mahatma Gandhi University
    Graduation: University of Calicut
    Memeber Since: Jan 2021
    Research Interests:Ternary and quaternary metal oxide nanomaterials

    2. Sarika V

    Fellowship: INSPIRE                                                                                                                                              
    Post Graduation: MES Kalladi College (University of Calicut)
    Graduation: MES Kalladi College (University of Calicut)
    Memeber Since: Aug 2021   
    Research Interests: Energetic Oxidizers

    3. Anusree T C

    Fellowship: GATE/Institute Fellowship
    Post Graduation: National Institute of Technology Calicut
    Graduation: Govt. College Madappally
    Memeber Since: Aug 2022  
    Research Interests: Thermoelectric Materials

    4. Santra Merin Saju

    Fellowship: JRF(ARMREB/DRDO)
    Post Graduation: Madras Christian College
    Graduation: BCM College Kottayam
    Memeber Since: Aug 2022  
    Research Interests: Energetic Nanomaterials

    5. K. Mohammad

    Memeber Since: Aug 2022
    Research Interests: Fused Pyrazole based Energetic Materials

    6. Anagh M Dilip

    Post Graduation: Malabar Christian College
    Graduation: Malabar Christian College
    Memeber Since: July 2023 
    Research Interests: Boron based energetic Nanomaterials

    7. Lajith K

    Sr. Scientific Assistant. A, VSSC/ISRO, Trivandrum
    Post Graduation: Karpagam Arts And Science College
    Graduation: Nirmalagiri College
    Memeber Since: Jan 2024
    Research Interests: Boron based energetic Nanomaterials

     

    Junior Research Fellow (SERB)

    Manju V. M.
    Post Graduation: University of Kerala
    Memeber Since: Aug 2022
    Research Interests: Energetic Oxidizers

     

    Post Graduate Students

    1. Theresa Thankachen
    Institute: National Institute of Technology Calicut
    Member Since : Dec 2023
    Topic: Micro-Bridge Initiators

    2. Aniket Khara
    Institute: National Institute of Technology Calicut
    Member Since: Dec 2023
    Topic: Nitrogen Rich Energetic Molecules

    3. Vaishna Kottilaveetil
    Institute: National Institute of Technology Calicut
    Member Since: Dec 2023
    Decompostion pathway of bis(3,4,5- trinitro-1H-pyrazol-1-yl)methane

     

    Internship Students

    1. Miswar Yousuf T

    Course: IMSc Chemistry
    Institute: Universidty of Hyderabad
    Memeber Since: June 2022
     

    Alumini

    Post Doctoral Fellow

    1. Dr. Dhanya B P

    PhD: CSIR-NIIST, Thiruvananthapuram, 2018
    Post Graduation: Mahatma Gandhi University
    Duration: Nov 2021 - June 2023 
    Research Interests:Synthesis of polynitro functionlized hetrocycles

    PG Project Students

    1. Anusree T C
    Institute: National Institute of Technology Calicut  
    Duration: Jan 2021- May 2021

    2. Sneha Rajeev
    Institute: National Institute of Technology Calicut  
    Duration Dec 2021- May2022
    Research Interests: 3DOM Metal Oxides for nanothermites

    3. Hiba
    Institute: National Institute of Technology Calicut  
    Duration Dec 2021- May2022
    Research Interests: 3DOM Metal Oxides for nanothermites

    4. Shalet N
    Institute: PSG College of Arts and Science
    Duration Feb 2022- May2022
    Research Interests: CoSb3 Synthesis

    5. Arya K B
    Institute: CMS College, Kottayam
    Duration : March 2022 - July 2022
    Research Interests: Polynitro functionlized aromatic compounds

    6. Parvathy M
    Institute: MPMMSN Trust College, Shoranur
    Duration : March 2022 - July 2022
    Research Interests: Co Based Nanomaterials

    7. Justin Alex Thomas
    Institute: National Institute of Technology Calicut
    Member Since : Dec 2022
    Electro Pyrotechnic Initiators

    8. Ashish Kumar Samal
    Institute: National Institute of Technology Calicut
    Member Since: Aug 2022
    Energetic Bridged tetrazoles

    Sponsored Projects

    At NITC

    (1) Title: Development of Oxidizers
          Agency: Defence Research and Development Organisation (DRDO)
          Board: ARMREB
          Duration: 2021-2024

    (2) Title: Chemical synthesis of filled low dimensional CoSb3 skutterudites based high figures of merit thermoelectric devices for IC engine‐driven vehicles
         Agency: Science and Engineering Research Board (SERB)
         Scheme: Startup Research Grant(SRG)
         Duration: 2021-2023
     

    At University of Hyderabad
     

    (1) Synthesis of a) DNPP, b) 3,6-dinitropyrazolo[4,3-c]pyrazole-1,4-diamine, c) 1,3,4,6-tetranitro-1,4-dihydropyrazolo[4,3-c]pyrazole and d) DNPP Derivatives
         Agency: Defence Research and Development Organisation (DRDO)
         Board: ER & IPR
         Funding: 1.57 crore    
         Duration: 5 years

    (2) Synthesis and characterization of Ammonium Dintramide (ADN) oxidizer
         Agency: Defence Research and Development Organisation (DRDO)
         Board: ER & IPR
         Funding: 71 Lakh     
         Duration: 4 years

    (3) Synthesis, characterisation of aluminium and plasmonic particles for NIR region for laser initiation of explosives
         Agency: Defence Research and Development Organisation (DRDO)
         Board: ER & IPR
         Funding: 1.22 crore    
         Duration: 5 years

    (4) Development and characterisation of metal-metal oxide nano-composites a) Al/CuOb) Al/Fe2O3c) Al/Bi2O3 d) Al/Viton
         e) Al/Teflon (Co-Investigator Prof. K. Muralidharan, School of Chemistry)
         Agency: Defence Research and Development Organisation (DRDO)
         Board: ER & IPR
         Funding: 82.14 lakh    
         Duration: 4 years

    • Anuj A. Vargeese, G. Rajanna, A process for the manufacture of high purity Ammonium dinitramide (ADN), Indian Patent 380348, 2021

    Professional Activities

    • Life Member, Combustion Institute (Indian Section)

    • Life Member, High Energy Material Society of India (HEMSI)

             NITC

    • Associate Dean (R&C) - (Feb 2024-present)
    • Coordinator, IPR Cell (CIEI) - (Jan 2023 - Feb 2024)
    • In charge, NMR Instrument Facility (CMC) –(March 2021- present)
    • Convener, HR Module IMS (Dec 2021-present)
    • Member, NBA Visit coordination committee (Three times)
    • Convener, SATHI proposal submission Committee
    • Purchase committee member, Department of Chemistry (July 2020-June 2022)
    • Purchase committee member, Liquid Nitrogen Plant

     

            University of Hyderabad

    • Project Monitoring & Review Committee (PMRC) of High energy materials research laboratory  (HEMRL/DRDO), Pune (2016-2019)
    • Member, Hazardous Waste Monitoring Committee, University of Hyderabad, (2019-2020)

    Ph. D. positions are available for highly motivated students

    Qualification: MSc Chemistry with CSIR/UGC -NET/GATE or Other Fellowships/funding

    Number of vacancies: 1

    1) Prof. K. Muralidharan
    School of Chemistry and ACRHEM
    University of Hyderabad
    Hyderabad - 500 046   

    2) Dr. T. R. Ravindran
    Scientific Officer-H and Head, Light Scattering Studies Section
    Professor, Homi Bhabha National Institute
    Materials Science Group
    Indira Gandhi Centre for Atomic Research
    Kalpakkam 603 102, India
     
    3) Dr. Shailendra Dahiwale
    Asst. Professor
    Department of Physics
    University of Pune
    Pune 411 007

    Education

    Ph. D. (University of Pune)
    Title of the Thesis: Studies on the crystal habit modification and morphology control of Ammonium Nitrate and Ammonium Perchlorate
    Advisors: Dr. V. N. Krishnamurthy & Dr. (Mrs.) S. S. Joshi

    M. Sc. (University of Pune)
    Title of the Thesis: Development of silicone based inhibitor for solid propellants
    Advisor: Dr. V. N. Krishnamurthy

     

    Research/Teaching Experience

    Assistant Professor (Feb 2020 -Present)
    Department of Chemistry,
    National Institute of Technology Calicut (NIT Calicut)

    Assistant Professor (May 2017-Feb 2020)
    Nanomaterials and Propellant Chemistry Laboratory
    Advanced Centre of Research in High Energy Materials (ACRHEM),
    University of Hyderabad

    Scientist (Co-terminus) (September 2014 - April 2017)
    Advanced Centre of Research in High Energy Materials (ACRHEM),
    University of Hyderabad

    Adhoc Lecturer (July 2011 - September 2014)
    Department of Chemistry
    National Institute of Technology Calicut 

    PURSE Postdoctoral Fellow (June 2010 - July 2011)
    With Prof. K. Muralidharan
    School of Chemistry &
    Advanced Centre of Research in High Energy Materials (ACRHEM),
    University of Hyderabad

    Research Associate (June 2009 - June 2010)
    With Prof. K. Muralidharan
    Advanced Centre of Research in High Energy Materials (ACRHEM),
    University of Hyderabad